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Working with Oxygen

Using Installing and Storing Oxygen Safely

This page provides information on the fire and explosion hazards in the use of oxygen. It is for anyone who uses oxygen gas in cylinders.

Hazards from oxygen

Oxygen gas in cylinders is used in gliding for breathing at high altitudes

The air we breathe contains about 21% oxygen. Without oxygen we would die in a matter of minutes. It may be hard to believe, but oxygen can also be dangerous. The dangers are fire and explosion.

Oxygen behaves differently to air, compressed air, nitrogen and other inert gases. It is very reactive. Pure oxygen, at high pressure, such as from a cylinder, can react violently with common materials such as oil and grease. Other materials may catch fire spontaneously. Nearly all materials including textiles, rubber and even metals will burn vigorously in oxygen.

Even a small increase in the oxygen level in the air to 24% can create a dangerous situation. It becomes easier to start a fire, which will then burn hotter and more fiercely than in normal air. It may be almost impossible to put the fire out. A leaking valve or hose in a poorly ventilated room or confined space can quickly increase the oxygen concentration to a dangerous level.

The main causes of fires and explosions when using oxygen are:

  •     oxygen enrichment from leaking equipment;
  •     use of materials not compatible with oxygen;
  •     use of oxygen in equipment not designed for oxygen service;
  •     incorrect or careless operation of oxygen equipment.

Beware of oxygen enrichment

Oxygen enrichment is the term often used to describe situations where the oxygen level is greater than in air. Oxygen is colourless, odourless and tasteless. The presence of an oxygen enriched atmosphere cannot be easily detected by the human senses. The main danger to people from an oxygen enriched atmosphere is that clothing or hair can easily catch fire, causing serious or even fatal burns. Smoking should be forbidden where oxygen is being used.

Oxygen enrichment is often the result of:

  •     leaks from damaged or poorly maintained hoses, pipes and valves;
  •     leaks from poor connections;
  •     opening valves deliberately or accidentally;
  •     not closing valves properly after use;
  •     poor ventilation where oxygen is being used.

Consequently, the main ways to prevent oxygen enrichment are to keep oxygen equipment in good condition and to take care when using it. Good ventilation will also reduce the risk of oxygen enrichment.

Oxygen enrichment can also result from the misuse of oxygen.

Never use oxygen for:

    cooling or refreshing the air in confined spaces;
    dusting benches, machinery or clothing.

If oxygen enrichment from an oxygen leak is suspected, the oxygen supply should be turned off. Cigarettes and open flames should be extinguished. The area should be well ventilated and the source of the leak identified and repaired. It is possible that oxygen may contaminate any clothing in the area. If this is suspected, the clothing should preferably be removed and taken outside for airing and ventilating.

Confined spaces

Some of the most serious oxygen-related incidents have involved damaged oxygen hoses leaking into confined spaces, where welding and burning operations were taking place. The workers’ oxygen enriched clothing caught fire, causing serious or fatal injuries.

Where the risk from oxygen enrichment is high, such as in a confined spacethe use of oxygen monitoring equipment is advisable.

Never use materials incompatible with oxygen

Some materials react explosively if they come into contact with pure oxygen at high pressure. Other materials may catch fire spontaneously. Such materials are incompatible with oxygen.

Equipment designed for oxygen service is made from materials and components that have been tested and proved to be compatible, and are safe for the purpose. The reasons for a particular design and choice of material are not always obvious. Using substitute materials or components, which appear to be similar but are not proven to be oxygen compatible, is extremely dangerous and has caused many accidents.

You need to take care when replacing:

  • O-rings and gaskets There are hundreds of different types of rubber and elastomer, and most are not compatible with oxygen.
  • Metal components Many metals and alloys are not suitable for use with oxygen.
  • Pressure regulators You must ensure that the pressure rating of the regulator is not less than the full cylinder supply pressure. If in doubt, check with the supplier or manufacturer.
  • Lubricants As a rule, lubricants should be avoided. Only lubricants that are made for oxygen service, and are specified by the equipment supplier, should be used.
  • Tape Tape should be avoided. Only tape that is marked as suitable for oxygen service, and is specified by the equipment supplier, should be used.
  • Other components In some cases, the materials may appear to be compatible but the shape and configuration of components may be important in minimising the fire risk. Only components approved by the manufacturer should be used when maintaining oxygen equipment. You should always ensure that high-pressure oxygen systems are designed, constucted, installed and commissioned by competent people who have specialised knowledge of the subject. All oxygen apparatus and equipment must be properly identified with the gas name and safe working pressure.

Never use oxygen in equipment not designed for it

Many serious accidents have been caused by using oxygen instead of other gases such as air, compressed air or nitrogen. Oxygen can react explosively with oils and greases. People have been injured or even killed when pumps, engines, tyres and pressure equipment have been blown apart by the explosion. Oxygen can also cause other materials to ignite spontaneously. The resulting fire can cause damage to equipment and injury to people.

You should never use oxygen for:

  •     driving pneumatic tools;
  •     inflating vehicle tyres;
  •     pressurising and purging systems;
  •     replacing air or inert gas;

Oxygen must not be introduced into any equipment unless it has been designed for oxygen service by competent people with specialist knowledge.

Take care with oxygen cylinders and equipment

If oxygen cylinders and equipment are used carelessly or incorrectly, then a fire may result. All users of oxygen should know and understand the dangers, and should receive training in the use of oxygen equipment. There are a number of precautions to follow when using oxygen equipment.

Oxygen cylinders

You should always:

  •     handle oxygen cylinders carefully.
  •     keep cylinders clamped to prevent them from falling over;
  •     store oxygen cylinders when not in use in a well ventilated storage area or compound, away from combustible materials


Oxygen equipment

You should always:

  •  open the valve slowly. Rapid opening, particularly of cylinder valves, can result in momentarily high oxygen velocities. Any particles will be pushed through the system very quickly, causing frictional heat. Alternatively, if the system has a dead end such as where a pressure regulator is connected to an oxygen cylinder, heat can be generated through compression of the oxygen. Both cases can result in a fire;
  •  ensure that the pressure adjusting screw of the pressure regulator is fully  unwound, so that the regulator outlet valve is closed before opening the oxygen cylinder valve, particularly when opening the cylinder valve for the first time after changing cylinders;
  •  ensure that cylinder valves are closed and piped supplies isolated whenever work is stopped. Do not try to cut off the supply of oxygen by nipping or kinking flexible hose when changing equipment
  •  maintain hoses and other equipment in good condition.

Leak tests can be carried out easily using a proprietary spray or liquid solution that is certified for use on oxygen systems. Soap or liquids that may contain grease should not be used.
Cleanliness

You should always:

  • keep oxygen equipment clean. Contamination by particulate matter, dust, sand, oils, greases or general atmospheric debris is a potential fire hazard. Portable equipment is particularly susceptible to contamination, and precautions should be taken to keep it clean;
  • use clean hands or gloves when assembling oxygen equipment, eg attaching the pressure regulator, making connections;
  • wear suitable clean clothing, free from oil and easily combustible contaminants.

    

General precautions

You should always:

  •     ensure that ventilation is adequate;
  •     check that fire extinguishers are in good condition and ready for use;
  •     check that escape routes are clear.

Summary of advice

  1. Be aware of the dangers of oxygen - if in doubt, ask.
  2. Prevent oxygen enrichment by ensuring that equipment is leak-tight and in good working order.
  3. Check that ventilation is adequate.
  4. Always use oxygen cylinders and equipment carefully and correctly.
  5. Always open oxygen cylinder valves slowly.
  6. Do not smoke where oxygen is being used.
  7. Never use replacement parts which have not been specifically approved for oxygen service.
  8. Never use oxygen equipment above the pressures certified by the manufacturer.
  9. Never use oil or grease to lubricate oxygen equipment.
  10. Never use oxygen in equipment which is not designed for oxygen service.

This information has been edited from the HMSO leaflet  Take care with Oxygen.